High-Test hypochlorite (HTH) is sold for chlorination of WATER
Category
MSDS
| Porduct Name | Sodium Hypo Chlorite 4-6 Percent |
| Part Number | RXSOL-40-1913-210 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
| Product name | Cas No | EC No | Weight | Formula |
| Sodium hypochlorite solution approximately 4 % w/v available chlorine EMPLURA® | 7681-52-9 | 231-668-3 | 74-439 | ClNaO |
| Signal Word | Danger |
| Hazard Statements | H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H410 Very toxic to aquatic life with long lasting effects |
| Precautionary statements | P234 Keep only in original packaging. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance |
| If inhaled | fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| Eye Contact | After eye contact rinse out with plenty of water. Remove contact lenses. |
| Swallowed | After swallowing make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | No data available |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture | Hydrogen chloride gas Sodium oxides Not combustible. Fire may cause evolution of: Hydrogen chloride gas Ambient fire may liberate hazardous vapours. |
| Further information | Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
| Advice on protection against fire and explosion | No data available |
| Incompatible materials | No data available |
| Hygiene measures | No data available |
| Advice on safe handling | For precautions see section 2.2 |
| Conditions for safe storage including any incompatibilities |
No data available |
| Storage conditions | No metal containers. Protected from light.Tightly closed. Do not store near acids. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510) 8B Non-combustible, corrosive hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Protective clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
| Respiratory protection |
Recommended Filter type Filter B-(P3) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
|
| Other Protection Measure | No data available |
| Physical state | Liquid |
| Colour | Light green |
| Odour | of chlorine |
| Odor Threshold | No data available |
| pH | 12 - 13 at 20 °C |
| Melting Point | -20 °C |
| Boiling Point | 102 °C at 1.013 hPa |
| Flash Point | 9,7 °C - closed cup - Regulation (EC) No. 440/2008, Annex, A.9 |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | 455,0 °C at 1.013 hPa - DIN 51794 |
| Decomposition temperature | Distillable in an undecomposed state at normal pressure. |
| Vapour pressure | 20 hPa at 20 °C |
| Viscosity | Dynamic 2,8 mPa.s at 20 °C |
| Density | 1,22 g/cm3 at 20 °C |
| Relative Density | No data available |
| Specific Gravity | No data available |
| Partition coefficient | Log Pow -0,77 - (Lit.), Bioaccumulation is not expected. |
| Explosive properties | No data available |
| Solubility | at 20 °C soluble |
| Ignition temperature | No data available |
| Particle characteristics | No data available |
| Reactivity | Contact with acids liberates toxic gas. |
| Chemical stability | heat-sensitive Sensitivity to light Sensitive to air. The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibilityof hazardous reactions | Risk of explosion with Acids hydrochloric acid nitrous gases Chlorine Nitric acid Cyanides Oxidizing agents Reducing agents oxalic acid Organic Substances Methanol urea Acetic anhydride Ammonia Millipore- 1.93607 Page 8 of 14 The life science business of Merck operates as MilliporeSigma in the US and Canada Amines formic acid Risk of ignition or formation of inflammable gases or vapours with: arsenic Violent reactions possible with: Generates dangerous gases or fumes in contact with: Acids The generally known reaction partners of water |
| Conditions to avoid | Avoid shock and friction. |
| Incompatible materials |
Metals
|
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | LD50 Oral - Rat - male - 1.100 mg/kg (OECD Test Guideline 401) Inhalation: No data available LD50 Dermal - Rabbit - male and female - > 20.000 mg/kg (OECD Test Guideline 402) |
| Skin corrosion/irritation | Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Serious eye damage/irritation | Causes serious eye damage. |
| Respiratory or skin sensitization | Guinea pig Not a skin sensitizer. (OECD Test Guideline 406) |
| Carcinogenicity | Did not show carcinogenic effects in animal experiment |
| Germ cell mutagenicity | Mutagenicity (micronucleus test) Species: Mouse - male negative |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure |
No data available
|
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice |
| Persistence and degradability | The methods for determining the biological degradability are not applicable to inorganic substances. |
| Toxicity to fish | LC50 - Pimephales promelas (fathead minnow) - 0,08 mg/l - 96 h Remarks: (Regulation (EC) No 1272/2008, Annex VI) (ECOTOX Database) |
| Toxicity to daphnia and other aquatic invertebrates | EC50 - Daphnia magna (Water flea) - 0,04 mg/l - 48 h Remarks: (Regulation (EC) No 1272/2008, Annex VI) (ECOTOX Database) |
| Toxicity | Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia similis (Water flea) - > 100 mg/l - 48 h (Regulation (EC) No. 440/2008, Annex, C.2) |
| Toxicity to bacteria | Static test EC50 - activated sludge - 77,1 mg/l - 3 h (OECD Test Guideline 209) Remarks: (ECHA) |
| Toxicity to algae | Static test ErC50 - Pseudokirchneriella subcapitata - 0,036 mg/l - 72 h (OECD Test Guideline 201) static test EC10 - Pseudokirchneriella subcapitata - 0,02 mg/l - 72 h (OECD Test Guideline 201 |
| Products Biodegradation | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Other adverse effects | Forms corrosive mixtures with water even if diluted. Harmful effect due to pH shift. Discharge into the environment must be avoided. |
| Product | No data available |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |
| UN number |
ADR/RID:1791 IMDG:1791 IATA:1791 |
| UN proper shipping name | ADR/RID:HYPOCHLORITE SOLUTION IMDG:HYPOCHLORITE SOLUTION IATA:HYPOCHLORITE SOLUTION |
| Transport hazard class(es) | ADR/RID:8 IMDG:8 IATA:8 |
| Packaging group | ADR/RID:ll IMDG:ll IATA:ll |
| Environmental hazards | ADR/RID:Yes IMDG Marine pollutant:Yes IATA: No |
| Special precautions for user | Tunnel restriction code (E) |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment was not carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |