Peracetic acid is an environmentally safe and versatile anti-microbial agent and a powerful antioxidant
Category
MSDS
| Product Name | Peracetic Acid 38 Percentage |
| Part Number | RXSOL-33-1267-250 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
Mixtures
| Component | Classification | Concentration |
| Acetic acid | ||
|
CAS-No. 64-19-7
EC-No 200-580-7
Index-No. 607-002-00-6
Registration 01-2119475328-30-
number XXXX
|
Flam. Liq. 3; Skin Corr.
1A; Eye Dam. 1; H226,
H314, H318
Concentration limits:
>= 90 %: Skin Corr. 1A,
H314; 25 - 90 %: Skin
Corr. 1B, H314; 10 - 25
%: Skin Irrit. 2, H315; 10
- 25 %: Eye Irrit. 2,
H319;
|
>= 30 - 50 % |
| Peracetic acid | ||
|
CAS-No. 79-21-0
EC-No. 201-186-8
Index-No. 607-094-00-8
|
Flam. Liq. 3; Org. Perox.
D; Acute Tox. 4; Skin
Corr. 1A; Eye Dam. 1;
Aquatic Acute 1; Aquatic
Chronic 1; H226, H242,
H302, H332, H312, H314,
H318, H400, H410
Concentration limits:
>= 1 %: STOT SE 3,
H335;
M-Factor - Aquatic Acute:
10
|
>= 30 - 50 % |
| Hydrogen Peroxide | ||
|
CAS-No. 7722-84-1
EC-No. 231-765-0
Index-No. 008-003-00-9
Registration 01-2119485845-22-
number xxxx
|
Ox. Liq. 1; Acute Tox. 4;
Skin Corr. 1A; Eye Dam.
1; STOT SE 3; Aquatic
Chronic 3; H271, H302,
H332, H314, H318, H335,
H412
Concentration limits:
>= 70 %: Ox. Liq. 1,
H271; 50 - 70 %: Ox.
Liq. 2, H272; >= 70 %:
Skin Corr. 1A, H314; 50 -
70 %: Skin Corr. 1B,
H314; 35 - 50 %: Skin
Irrit. 2, H315; 8 - 50 %:
Eye Dam. 1, H318; 5 - 8
%: Eye Irrit. 2, H319; >=
35 %: STOT SE 3, H335;
> 40 - 50 %: Ox. Liq. 3,
H272;
|
>= 3 - 5 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
|
Self-reactive substances and
mixtures, (Type D)
|
H242: Heating may cause a fire. |
| Organic peroxides, (Type D) | H242: Heating may cause a fire. |
| Acute toxicity, (Category 3) | H301: Toxic if swallowed. |
| Skin corrosion, (Category 1) | H314: Causes severe skin burns and eye damage. |
| Serious eye damage, (Category 1) | H318: Causes serious eye damage. |
|
Specific target organ toxicity -
single exposure, (Category 3),
Respiratory system
|
H335: May cause respiratory irritation. |
|
Short-term (acute) aquatic
hazard, (Category 1)
|
H400: Very toxic to aquatic life. |
|
Long-term (chronic) aquatic
hazard, (Category 1)
|
H410: Very toxic to aquatic life with long lasting effects. |
Label elements
| Signal Word | Danger |
|
Hazard Statements |
H242 Heating may cause a fire.
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
|
|
Precautionary Statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
|
| Supplemental Hazard Statements | None |
| Reduced Labeling (= 125 ml) | |
| Signal Word | Danger |
| Hazard statement |
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
|
| Precautionary statement |
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
|
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
Description of first aid measures
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Call in physician. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| If swallowed | If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
Extinguishing media
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Carbon oxides
Combustible.
Fire-promoting. Keep away from combustible materials.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
|
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information |
Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.
|
| Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
|
| Environmental precautions | Do not let product enter drains. |
| Methods and materials for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
| Reference to other sections | For disposal see section 13. |
Precautions for safe handling
| Advice on safe handling | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
|
| Conditions for safe storage, including any incompatibilities | |
| Storage conditions |
Tightly closed. Keep locked up or in an area accessible only to qualified or authorized
persons. Separately or together with other organic peroxides only and away from sources of ignition and heat.
Recommended storage temperature see product label.
|
| Storage class | Storage class (TRGS 510): 5.2: Organic peroxides and self-reacting hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Control parameters
Ingredients with workplace control parameters
Exposure controls
Personal protective equipment
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Chloroprene
Minimum layer thickness: 0,65 mm
Break through time: 480 min
Material tested:KCL 720 Camapren®
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Latex gloves
Minimum layer thickness: 0,6 mm
Break through time: 60 min
Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M). |
| Body Protection | Acid-resistant protective clothing |
| Respiratory protection |
Required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type: Filter type P3
The entre peneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Liquid |
| Colour | Colorless |
| Odor | Stinging |
| Melting point/freezing point | Melting point: ca.-37 °C |
| Initial boiling point and boiling range | Not applicable |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits | No data available |
| Flash point | 62 °C |
| Autoignition temperature | No data available |
| Decomposition temperature |
> 60 °C
Type D
|
| pH | ca.1 at 20 °C |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | at 20 °C soluble |
| Partition coefficient: n-octanol/water | No data available |
| Vapor pressure | ca.14 hPa at 20 °C |
| Density | ca.1,14 g/cm3 at 20 °C |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | Not classified as explosive. |
| Oxidizing properties | Oxidizing potential |
| Other safety information | No data available |
| Reactivity |
Forms explosive mixtures with air on intense heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
|
| Chemical stability |
Stabilised
In case of decomposition in closed containers and tubes risk of bursting due to buildup of overpressure.
The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibility of hazardous reactions |
Risk of explosion with:
Heavy metal salts
Reducing agents
Organic Substances
Amines
combustible substances
Acetic anhydride
Strong oxidizing agents
Peroxides
potassium permanganate
perchloric acid
phosphorus halides
Alkali metals
alkali salts
Alkaline earth metals
Metals
metallic oxides
Metallic salts
nonmetals
nonmetallic oxides
Aldehydes
Ammonia
hydrazine and derivatives
hydrides
Ether
anhydrides
alkenes
organic nitro compounds
Brass
Impurities
Exothermic reaction with:
Ether
alkalines
mineral acids
Nitric acid
Alcohols
chromosulfuric acid
halogen-halogen compounds
chlorosulfonic acid
Tetrahydrofuran
metallic chlorides
with
Risk of ignition or formation of inflammable gases or vapours with:
Solvent
Hydrocarbons
fuming sulfuric acid
|
| Conditions to avoid |
Heating (explosive decomposition).
Strong heating.
|
| Incompatible materials |
Various plastics
|
| Hazardous decomposition products | In the event of fire: see section 5 |
Information on toxicological effects
| Acute toxicity |
LD50 Oral - Rat - 263 mg/kg
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of
perforation of the esophagus and the stomach.
Acute toxicity estimate Inhalation - 4 h - > 20 mg/l - vapor(Calculation method)
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of
respiratory tract
Acute toxicity estimate Dermal - > 2.000 mg/kg
(Calculation method)
|
| Skin corrosion/irritation | No data available |
| Serious eye damage/eye irritation |
Remarks: Mixture causes serious eye damage.
Risk of blindness!
|
| Respiratory or skin sensitization | No data available |
| Germ cell mutagenicity |
Test Type: Mutagenicity (mammal cell test): chromosome aberration.
Method: OECD Test Guideline 473
Result: negative
|
| Carcinogenicity | No data available |
| Reproductive toxicity |
No data available
|
| Specific target organ toxicity - single exposure | Mixture may cause respiratory irritation. |
| Specific target organ toxicity - repeated exposure |
No data available
|
| Aspiration hazard | No data available |
| Additional Information | |
|
Endocrine disrupting properties
Product
|
|
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.
|
| Toxicity | No data available |
| Persistence and degradability | No data available |
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher |
| Endocrine disrupting properties | |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects |
Biological effects:
Bactericidal effect.
Fungicide
Discharge into the environment must be avoided.
|
| Waste treatment Method | No data available |
| UN number | ADR/RID:3105 IMDG:3105 IATA: 3105 |
| UN proper shipping name |
ADR/RID: ORGANIC PEROXIDE TYPE D, LIQUID (PEROXYACETIC ACID, TYPE D)
IMDG: ORGANIC PEROXIDE TYPE D, LIQUID (PEROXYACETIC ACID, TYPE D)
IATA: Organic peroxide type D, liquid (Peroxyacetic acid)
Special Provisions: “Keep away from heat” label required.
|
| Transport hazard class(es) | ADR/RID:5.2 (8) IMDG: 5.2 (8) IATA:5.2 (8) |
| Packaging group | ADR/RID: lII IMDG: IIl IATA:IIl |
| Environmental hazards | ADR/RID: no IMDG Marine pollutant: no IATA: no |
| Special precautions for user | |
| Tunnel restriction code | (D) |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Authorisations and/or restrictions on use | |
| Regulation (EU) 2019/1148 on the marketing and use of explosives precursors | Hydrogen Peroxide |
|
National legislation
Seveso III: Directive 2012/18/EU of the
European Parliament and of the Council
on the control of major-accident hazards
involving dangerous substances.
|
H2 ACUTE TOXIC
P6b SELF-REACTIVE
SUBSTANCES AND
MIXTURES and ORGANIC
PEROXIDES
E1 ENVIRONMENTAL HAZARDS
|
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. |