Morpholine

99%-99.5% pure material can be use as Coating Auxiliary Agents, Plastic Auxiliary Agents, Rubber Auxiliary Agents, Surfactants, Textile Auxiliary Agents, Water Treatment Chemicals
Category

Morpholine classified as Boiler chemicals. Morpholine available pack is in 5 ltr to 210 Ltr. 

Its pH adjusting qualities then become distributed throughout the steam plant to provide corrosionprotection. Morpholine is often used in conjunction with low concentrations of hydrazine or ammonia to provide a comprehensive all-volatile treatment chemistry for corrosion protection for the steam systems of such plants. Morpholine decomposes reasonably slowly in the absence of oxygen at the high temperatures and pressures in these steam systems.
 

Coating Auxiliary Agents, Plastic Auxiliary Agents, Rubber Auxiliary Agents, Surfactants, Textile Auxiliary Agents, Water Treatment Chemicals

Purity ::: 99%-99.5%

Application

Also widely used as a fruit coating ::: 


Morpholine is used as a chemical emulsifier in the process of waxing fruit. Naturally, fruits make waxes to protect against insects and fungal contamination, but this can be lost as the fruit is cleaned. A small amount of new wax is applied to replace it. Morpholine is used as an emulsifier and solubility aid for shellac, which is used as a wax for fruit coating.

 

Morpholine derivatives used as agricultural fungicides in cereals are known as ergosterol biosynthesis inhibitors.

Dose


Morpholine is organic chemicals which have amine group and basic in nature. Morpholine is water soluble and most commonly used as vegetable and fruit coating chemicals compound as morpholine approved by FDA  to use as coating on food item.


Morpholine also used in Bolier steam industries as pH balancing compound to provide corrosion protection towards all metalic surface concern. Its uses is very simple as morpholine is water soluble in all proportion. Morpholine also can be use with hydrazine and others Boiler Water Treatment Chemicals.


Shellac easily dissolved in Morpholine during fruist and vegetable coating process, Now a days wax coating process is common to protect fruits and vegetable from fungal / alage contamination.

Technical specifications

 

MORPHOLINE
Test Results

Odour

amine-like
pH value
10.6 (5 g/l, 20°C)
Melting point
-5 °C
Boiling point
128 - 130 °C
Flash point
32 °C
Lower explosion limit
1.4% (V)
Upper explosion limit
13.1% (V)
Ignition temperature
275 °C
Vapour pressure
10 mbar (20 °C)
Density
1.00 g/cm3 (20 °C)
Solubility in water
(20 °C)
Viscocity, dynamic
2.3 mPa.s (20 °C)
Note
 
PRODUCT NAME  : MORPHOLINE
CAS number       : 110-91-8
UN number      : 2054
Formula       : C4H8ONH  or C4H9NO
Odour      : AMINE LIKE
Solubility in water      : COMPLETE
Density        : 1.002   at 20 OC
Boiling point          : 128 OC
Melting point       : -5 OC
Viscosity         :  2.23 cp at 20 OC
Flashpoint       : 37 OC
Explosive limits     :  
Vapour pressure       : 11 mbar at 20 OC
Skin absorption/irritation           : YES
TLV       Country  NL             Year  1995        : 20 S ppm              70 S     mg/m3
Pollution category    1994        :  D
 
Remarks / Precaution

Our regular customer of morpholine getting advantage of our pure imported morpholine as per there customized packing and requirements.

Packing sizes
Marpholine Available in 25, 50 , 210 ltrs pack
MSDS

 

Product Name Morpholine
Part Number RXSOL-40-1382-210
Synonym Tetrahydro-2H-1,4-oxazine
Chemical Formula C4H9NO

Company Details:

RX MARINE INTERNATIONAL
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VASHI ,NEW BOMBAY 400703 INDIA

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Name

                CAS #

         % by Weight

Chem Formula R Phrases

Morpholine

              110-91-8

                 100

C4H9NO R10 R20/21/22 R34

Toxicological Data on Ingredients : Morpholine: ORAL (LD50): Acute: 1450 mg/kg [Rat]. 525 mg/kg [Mouse]. DERMAL (LD50): Acute: 500 mg/kg [Rabbit].
VAPOR (LC50): Acute: 11313.7 ppm 4 hour(s) [Rat].

Potential Acute Health Effects Very hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,occasionally, blistering.
Potential Chronic Health Effects 445°C (833°F)Very hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of
ingestion, of inhalation.CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation. 

Eye Contact Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protecting your own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, such as the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.Cold water may be used. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. 
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti bacterial cream.    Seek immediate medical attention. 
Inhalation Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
Ingestion Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. 
Serious Ingestion Not available.

 

Flammability of the Product Flammable.
Auto-Ignition Temperature 310°C (590°F)
Flash Points CLOSED CUP: 35°C (95°F) OPEN CUP: 38°C (100.4°F).
Flammable Limits LOWER: 1.8% UPPER: 11.2%
Products of Combustion These products are carbon oxides (CO, CO2),  nitrogen oxides (NO, NO2...).Fire Hazards in Presence of Various Substances:Not available Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions Flammable liquid, soluble or dispersed in water.
SMALL FIRE Use DRY chemical powder.
LARGE FIRE Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto ignition or explosion.
Special Remarks on Fire Hazards Not available.
Special Remarks on Explosion Hazards Not Available

 

Small Spill Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if witout risk. Absorb with DRY earth, sand or other non combustible material. Do not get water inside container. Do not touch spilled material.Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV.Check TLV on the MSDS and with local authorities.

Precautions

Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all       equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Never add water to this product In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes

Storage

Flammable materials should be stored in a separate safety storage cabinet or room.
Keep away from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing material.A refrigerated room would be preferable for materials with a flash point lower than37.8°C (100°F).

 

Engineering Control

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. 

Personal Protection

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Exposure Limits

TWA: 20 CEIL: 30 (ppm) TWA: 70 CEIL: 105 (mg/m3) Consult local authorities for
acceptable exposure limits. 

Physical state and appearance : Liquid. (Oily liquid.)
Odor : Amine like. (Slight.)
Taste : Not available.
Molecular Weight : 87.12 g/mole
Color   Clear
pH (1% soln/water) : Not Available
Boiling Point : 128.19°C (262.7°F)
Melting Point :  -4.9°C (23.2°F)
Critical Temperature : Not available.
Specific Gravity : 0.9168 (Water = 1)
Vapor Pressure : 7 mm of Hg (@ 20°C)
Vapor Density : 3 (Air = 1)
Volatility : 100% (v/v).
Odor Threshold :  0.1 ppm
Water/Oil Dist. Coeff : Not available.
Ionicity (in Water) : Not available.
Dispersion Properties : See solubility in water.
Solubility : Easily soluble in cold water.

Stability The product is stable.
Instability Temperature Not available.
Conditions of Instability Not Available.
Incompatibility with various substances Not Available.
Corrosivity Non-corrosive in presence of glass.
Special Remarks on Reactivity Not Available.
Special Remarks on Corrosivity Not available.
Polymerization No

Routes of Entry

Dermal contact. Eye contact. Inhalation. Ingestion

Toxicity to Animals

THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4 HOUR EXPOSURE. Acute oral toxicity (LD50): 525 mg/kg [Mouse]. Acute dermal toxicity (LD50): 500 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 11313.7 ppm 4 hour(s)[Rat].

Chronic Effects on Humans

The substance is toxic to lungs, mucous membranes.

Other Toxic Effects on Humans

 Very hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals

Not available.

Special Remarks on Chronic Effects on Humans 

Not available.

 

Special Remarks on other Toxic Effects on Humans  Not available.

ECOTOXICITY EFFECTS:

ACUTE TOXICITY: None known
MOBILITY: NA
PERSISTENCE AND DEGRADABILITY: None known
 
BIOACCUMULATIVE POTENTIAL: Is not known to accumulate


 

WASTE TREATMENT: Dispose of within current local and state regulations.
No special method required.
PACKAGING TREATMENT: Consult federal, state, and local regulations regarding the proper disposal of emptied containers.
RCRA HAZARD CLASS:

  NA

U.S. DEPARTMENT OF TRANSPORTATION

Chemicals Not Hazardous
PROPER SHIPPING
NAME:
Otherwise Indexed
(NOI)
 
HAZARD CLASS: Not Regulated
 
ID NUMBER:  NA
LABEL STATEMENT: None


WATER TRANSPORTATION

 

Chemicals Not Hazardous
PROPER SHIPPING
NAME:
Otherwise Indexed
(NOI)
HAZARD CLASS: Not Regulated
ID NUMBER:  NA
LABEL
STATEMENT:
None

 
AIR TRANSPORTATION

 

Chemicals Not Hazardous

 

PROPER SHIPPING
NAME:
Otherwise Indexed
 
HAZARD CLASS: Not Regulated
ID NUMBER: NA
LABEL None

Preparation does not contain ingredients listed as a dangerous substance in Annex 1 of the EEC directive 67/548.

KEEP OUT OF REACH OF CHILDREN

Although the information and recommendations set forth in this sheet are believed to be correct as of the date hereof, Rx Marine International makes no representation as to the completeness or accuracy of such information and recommendations. Rx Marine International shall in no event be responsible for any damages of whatsoever nature directly or indirectly resulting from the publication or use of or reliance upon such information and recommendations. You are encouraged to advise anyone working with or exposed to such products of the information contained herein.

No Warranty, either expressed or implied, of merchantability or fitness or of any other nature with respect to the product or to the information and recommendations herein made hereunder.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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