Isobutanol

Isobutanol
Isobutanol is an organic compound with the formula (CH₃)₂CHCH₂OH. This colorless, flammable liquid with a characteristic smell is mainly used as a solvent either directly or as its esters. Its isomers, the other butanols, include n-butanol, 2-butanol, and tert-butanol, all of which are important industrially.

Isobutanol appears as a clear colorless liquid with a sweet odor. Flash point 85 - 100°F. Less dense than water. Vapors heavier than air.

Isobutanol is an alkyl alcohol that is propan-1-ol substituted by a methyl group at position 2. It has a role as a Saccharomyces cerevisiae metabolite. It is a primary alcohol and an alkyl alcohol. It derives from a hydride of an isobutane.

Isobutanol is worth more to refiners than ethanol because it has 26% more energy. Unlike ethanol that is 100% miscible with water, isobutanol has limited solubility, and among other advantages, it doesn’t cause stress cracking in pipelines. Also, its lower oxygen content enables greater amounts to be blended into gasoline. It overcomes the blend wall limitations of ethanol by producing a similar grade of gasoline at only 2.7% oxygen content for refiners. It qualifies as an Advanced Biofuel under the Reformulated Fuel Standard. It can be produced with genetically modified microorganisms by the ABE process.

 

Formula: C4H10O
Boiling point: 108 °C
Density: 802 kg/m³
Molar mass: 74.122 g/mol
Classification: Organic compound
Application

Isobutanol is an important chemical used for producing antioxidants, paint solvents, flavors, and synthetic rubber.
It can also be used as fuel additive to improve the fuel quality. I-butanol is a petroleum-derived product and is produced mainly through propylene carbonylation.

Additionally, it can be used as an intermediate in synthesis of many valuable chemicals, such as isobutene, MTBE, and isooctane. Isobutanol is a more desirable gasoline substitute compared with ethanol due to its higher energy density, higher octane numbers, lower hygroscopicity, and lower volatility.

Isobutanol is used as a raw material for coating resins, Isobutyl acrylate, isobutyl acetate, isobutyl methacrylate, and paint thinners. On the other hand, it is widely used as a solvent because many organic materials are soluble in it.

Dose

Iso-Butanol (IBA) is a clear liquid with a characteristic odor. It is miscible with all common solvents. It is obtained in Oxo Synthesis of Propylene (C3H6) and Synthesis gas (H2+CO).

Technical specifications

Appearance (Clarity): Clear

Appearance (Colour): Colourless

Appearance (Form): Liquid

Density (g/ml) @ 20°C: 0.801 - 0.804

Refractive Index (20°C): 1.396 - 1.397

Boiling Range: 106-109°C

Purity (%): 99.9%

Assay (%): 99%

Solubility: Slightly soluble in water

Applications: Manufacturing antioxidants, paint solvents, flavors, and synthetic rubber

Cas-No: 78-83-1

Note
  • Excellent Solvent for acid-curable lacquers and baking finishes derived from Urea, Melamine or Phenolic resins
  • Reduces Viscosity and thus improves the brush ability and flow when added in small portions to Alkyl resin paints 
Remarks / Precaution

Isobutanol suppliers and exporters in India, Isobutanol suppliers in Mumbai, Isobutanol suppliers in Kandla, Isobutanol suppliers in Kolkata, Isobutanol suppliers in Vishakhapatnam, Isobutanol suppliers in Chennai, Isobutanol suppliers in Fujairah, Oman, Sohar, Dubai, Canada BC, Nairobi Kenya Africa.

RXSOL Isobutanol exporters in India, Isobutanol exporters in Mumbai, Mundra, Kandla, Kolkata, Howrah, Vishakhapatnam, Chennai. Isobutanol dealers in Dubai, Isobutanol dealers in Fujairah, Isobutanol dealers in Oman, Isobutanol dealers in Canda BC

Packing sizes
210 Ltrs
MSDS

Product Name RXSOL-19-1570-210
Product Type   Iso Butanol

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Kolkata, Chennai, Fujairah, Muscat, Nairobi, Visakhapatnam

Phone +91 22 65113333 / 5555 / 9999 / 27815540
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email mail@rxmarine.com
Website www.rxmarine.com

Chemical Name

CAS Number

EC Number

Index number

Butanol

78-83-1

201-148-0

603-108-00-1

Hazard description:
Information concerning particular hazards for human and environment:
R 10 Flammable.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
R 67 Vapours may cause drowsiness and dizziness.

After inhalation

In case of unconsciousness place patient stably in side position for transportation.

After skin contact

Immediately wash with water and soap and rinse thoroughly.

After eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

After swallowing

If symptoms persist consult doctor.

Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents: Water with full jet
Protective equipment: No special measures required.

Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting: Dilute with plenty of water. Ensure adequate ventilation.

Handling:
Information for safe handling: No special requirement
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep container tightly sealed.

Additional information about design of technical facilities: No further data; see item 7.

Ingredients with limit values that require monitoring at the workplace:
78-83-1 butanol
PEL (USA)
REL (USA)
TLV (USA)
WEL (Great Britain)
300 mg/m³, 100 ppm
150 mg/m³, 50 ppm
152 mg/m³, 50 ppm
Short-term value: 231 mg/m³, 75 ppm
Long-term value: 154 mg/m³, 50 ppm

Additional information: The lists valid during the making were used as basis.
Personal protective equipment:
General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin.
Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be   observed.
Eye protection: Tightly sealed goggles

General Information

Form

Fluid

Colour

Colourless

Odour

Sweetish

Change in condition

Melting point/Melting range

-108°C

Boiling point/Boiling range

108°C

Flash point

24°C

Ignition temperature 390°C

Danger of explosion

Product is not explosive. However, formation of explosive air/vapour mixtures are possible.

Explosion limits:
Lower 1.7 Vol %
Upper 12 Vol %
Vapour pressure at 20°C 12 hPa
Density at 20°C 0.8016 g/cm³
Solubility in / Miscibility with water at 20°C 100 g/l
pH-value (4 g/l) at 20°C 7
Viscosity:
Dynamic 3.95 mPas

Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Dangerous reactions No dangerous reactions known.
Dangerous decomposition products: No dangerous decomposition products known.

Acute toxicity:
LD/LC50 values relevant for classification:  

Oral

Dermal

LD50

LD50

2460 mg/kg (rat)

3400 mg/kg (rabbit)

Primary irritant effect:
on the skin Irritant to skin and mucous membranes.
on the eye Strong irritant with the danger of severe eye injury.
Sensitization No sensitizing effects known.

General notes: Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

Product:
Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging: Recommendation: Disposal must be made according to official regulations.

Land transport ADR/RID (cross-border)
  ADR/RID class 3 Flammable liquids.
  Danger code (Kemler) 30
  UN-Number 1212
  Packaging group III
  Hazard label 3
  Description of goods 1212 ISOBUTANOL (ISOBUTYL ALCOHOL)
Maritime transport IMDG
  IMDG Class 3
  UN Number 1212
  Label 3
  Packaging group III
  EMS Number F-E,S-D
  Marine pollutant No
  Proper shipping name ISOBUTANOL (ISOBUTYL ALCOHOL)
Air transport ICAO-TI and IATA-DGR
  ICAO/IATA Class 3
  UN/ID Number 1212
  Label 3
  Packaging group II
  Proper shipping name ISOBUTANOL (ISOBUTYL ALCOHOL)

Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
Risk phrases:
10 Flammable.
37/38 Irritating to respiratory system and skin.
41 Risk of serious damage to eyes.
67 Vapours may cause drowsiness and dizziness.
Safety phrases:
2 Keep out of the reach of children.
7/9 Keep container tightly closed and in a well-ventilated place.
13 Keep away from food, drink and animal feedingstuffs.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

This information is based on our present knowledge.However, this shall not constitute a guarantee for anys pecific product features and shall not establish a legally valid contractual relationship.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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