Hydrogen peroxide is unstable, decomposing readily to oxygen and water with release of heat. Although nonflammable
Category
MSDS
| Product Name | Hydrogen Peroxide |
| Part Number | RXSOL-40-1630-120 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.comA |
| Chemical Name | CAS | EC number | Weight |
| Hydrogen Peroxide | 7722-84-1 | 231-765-0 | >= 30 - 35 % |
| Signal Word | Danger |
| Hazard Statements | H318 Causes serious eye damage. |
| Precautionary statements | P280 Wear eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Classification of the substance or mixture | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
| Supplemental Hazard Statements | None. |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. |
| Eye Contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| Swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
| Ingestion | Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
| Flash Point | Dry powder Dry sand |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Nature of decomposition products not known. Not combustible. |
| Further information | Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical | Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Enviromental Precaution | Do not empty into drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills.Observe possible material restrictions (see sections 7 and 10).Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595). Dispose of properly. Clean up affected area. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition. |
| Incompatible materials | Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Precautions for safe handling | Observe label precautions. |
| Storage conditions | No metal containers. Close containers in such a way to enable internal pressure to escape (e.g. excess pressure valve). Tightly closed. Protected from light. Do not store near combustible materials. Recommended storage temperature see product label.No metal containers. Close containers in such a way to enable internal pressure to escape (e.g. excess pressure valve). Tightly closed. Protected from light. Do not store near combustible materials. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510): 5.1B: Oxidizing hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Requirements for storage | Keep in cool and store under shade. |
| Exposure controls | Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
| Control parameters | Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. |
| Engineering Control | Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
| Eye/face protection | Tightly fitting safety goggles |
| Body Protection | Protective clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Latex gloves Minimum layer thickness: 0,6 mm Break through time: 480 min Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
| Respiratory protection | Recommended Filter type: filter NO The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not empty into drains. |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | Slight |
| Odor Threshold | No data available |
| pH | 2 - 4 at 100% at 20 °C |
| Melting Point | -26 °C |
| Boiling Point | 107 °C at 1.013 hPa |
| Flash Point | No data available |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | > 100 °C |
| Vapour pressure | ca.18 hPa at 20 °C |
| Density | 1,11 g/cm3 at 20 °C |
| Relative Density | No data available |
| Relative vapor density | No data available |
| Freezing point | No data available |
| Viscosity | No data available |
| Partition coefficient | No data available |
| Explosive properties | No data available |
| Solubility | No data available |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Reactivity | Has a fire-promoting effect due to release of oxygen. |
| Stability | heat-sensitive Sensitivity to light Contains the following stabilizer(s): Disodium pyrophosphate (0,015 %) phosphoric acid (0,01 %) Ammonium nitrate (0,006 %) |
| Possibility of hazardous reactions | Risk of explosion with: Acetaldehyde Acetone Activated charcoal Alcohols formic acid Ammonia combustible substances vinyl acetate Organic Substances Powdered metals Dust hydrazine and derivatives hydrides Ether Potassium anilines Metallic salts acetic acid Acetic anhydride Formaldehyde furfuryl alcohol oils sodium Lithium lithium aluminium hydride organic solvents Magnesium metallic oxides Methanol Reducing agents Oxides of phosphorus butanol with Sulphuric acid alkali hydroxides with Heavy metals Exothermic reaction with: alkali hydroxides antimony sulfide tin (II) chloride Sulfides 3-BROMO - 5 -CHLORO - 4 -HYDROXYBENZALDEHYDE nitric acid (conc.) ethanol glycerol Potassium hydroxide phosphorus metallic oxides Sodium hydroxide Aldehydes nonmetals nonmetallic oxides strong alkalis Amines Acids Oxidizing agents alkali salts Alkali metals Alkaline earth metals iodides peroxi compounds Brass organic nitro compounds phenol with metal catalysts Risk of ignition or formation of inflammable gases or vapours with: potassium permanganate Wood/Sawdust vinyl acetate with Catalyst |
| Conditions to avoid | Heating. |
| Incompatible materials | Metals |
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | LD50 Oral - Rat - female - 693,7 mg/kg (OECD Test Guideline 401) Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor (Expert judgment) LD50 Dermal - Rabbit - male and female - > 2.000 mg/kg (US-EPA) |
| Skin corrosion/irritation | Remarks: Causes severe burns. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Serious eye damage/eye irritation | Remarks: Causes serious eye damage. |
| Respiratory or skin sensitization | Maximization Test - Guinea pig Result: negative (OECD Test Guideline 406) |
| Toxic Effects on Human | May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | Method: OECD Test Guideline 474 Species: Mouse - male and female - Bone marrow Result: negative |
| Reproductive toxicity | Suspected of damaging fertility or the unborn child. |
| Specific target organ toxicity - single exposure | Inhalation - May cause respiratory irritation. - Respiratory Tract |
| Special Remarks on other Toxi Effects on Humans | Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - NOAEL (No observed adverse effect level) - 100 mg/kg - LOAEL (Lowest observed adverse effect level) - 225 mg/kg Remarks: The value is given in analogy to the following substances: ammonium bromide RTECS: VZ3150000 Effects due to ingestion may include:, sedation To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Systemic effects: Tiredness After uptake of large quantities: ataxia (impaired locomotor coordination) confusion Convulsions Coma However, when the product is handled appropriately, hazardous effects are unlikely to occur. Handle in accordance with good industrial hygiene and safety practice. |
| Bioaccumulative potential | No data available |
| Persistence and degradability | Biodegradability Remarks: No data available |
| Toxicity to fish | Semi-static test LC50 - Pimephales promelas (fathead minnow) - 16,4 mg/l - 96 h (US-EPA) |
| Toxicity to daphnia and other aquatic invertebrates | Semi-static test LC50 - Daphnia pulex (Water flea) - 2,4 mg/l - 48 h (US-EPA) |
| Toxicity to algae | Static test ErC50 - Skeletonema costatum (marine diatom) - 1,38 mg/l - 72 h Remarks: (ECHA) static test NOEC - Skeletonema costatum (marine diatom) - 0,63 mg/l - 72 h Remarks: (ECHA) |
| Toxicity to bacteria | Static test EC50 - activated sludge - 466 mg/l - 30 min (OECD Test Guideline 209) static test EC50 - activated sludge - > 1.000 mg/l - 3 h (OECD Test Guideline 209) |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No interference with wastewater treatment plants are to be expected when used properly. Discharge into the environment must be avoided. No data available |
| Disposal methods | The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
| Contaminated packaging | Dispose of as unused product. |
| Waste treatment Method | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| UN number | ADR/RID: 2014 IMDG: 2014 IATA: 2014 |
| UN proper shipping name |
ADR/RID:HYDROGEN PEROXIDE, AQUEOUS SOLUTION IMDG: HYDROGEN PEROXIDE, AQUEOUS SOLUTION IATA:HYDROGEN PEROXIDE, AQUEOUS SOLUTION |
| Transport hazard class(es) | ADR/RID: 5.1 (8) IMDG: 5.1 (8) IATA: 5.1 (8) |
| Packaging group | ADR/RID: II IMDG: II IATA: II |
| Environmental hazards | ADR/RID: NO IMDG: NO IATA: NO |
| Further information | No data available |
| Inventory status | Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Authorisations and/or restrictions on use | Regulation (EU) 2019/1148 on the marketing and use of explosives precursors : Hydrogen Peroxide Regulation (EU) 2019/1148 on the marketing and use of explosives precursors : Ammonium nitrate |
| National legislation | Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC : ENVIRONMENTAL HAZARDS |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment has been carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |