Hydrochloric Acid 37%

Hydrochloric acid is the aqueous solution of hydrogen chloride gas (HCl). It is a strong acid, and the major component of gastric acid. It is also widely used in industry. Hydrochloric acid must be handled with appropriate safety precautions because
Category
MSDS

Porduct Name               Hydrochloric Acid 37% 
Part Number   RXSOL-33-1525-220

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email mail@rxmarine.com
Website www.rxmraine.com

Product name       Cas No                        EC No              Weight                         Formula                   
Hydrochloric acid 7647-01-0 231-595-7 >= 30 - 50 % HCl
Signal Word  Danger
Hazard Statements H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation.
Precautionary statements   P234 Keep only in original packaging. P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of  the substance    or  mixture No data available
Supplemental Hazard    Statements No data available
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Contact with liquid or refrigerated gas can cause cold burns and frostbite. Lachrymator.The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

General advice First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled After inhalation fresh air. Call in physician.
Eye Contact  After eye contact rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses
Swallowed After swallowing make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise
Skin Contact   In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Inhalation No data available
Ingestion No data available
Most important    symptoms and effects,  both acute and delaye  The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical    attention and special treatment needed  No data available

Flammability                                                  No data available
Suitable extinguishing media  Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 
Special hazards arising from the substance or mixture  Hydrogen chloride gas Not combustible. Ambient fire may liberate hazardous vapours..
Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion
products
No data available
Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Protective Equipment No data available
Specific Hazards Arising from the Chemical No data available

Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8
Spillage No data available
Personal Protection No data available
Enviromental Precaution Do not let product enter drains. Risk of explosion.
Methods and materials for
containment and cleaning
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquidabsorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area
Reference to other sections    For disposal see section 13.

Advice on protection against      fire and    explosion No data available
Incompatible materials  No data available
Hygiene measures No data available.
Advice on safe handling  For precautions see section 2.2.
Conditions for safe storage including any  incompatibilities 

No data available

Storage conditions No metal containers. Tightly closed.
Storage class Storage class (TRGS 510) 8B Non-combustible, corrosive hazardous materials
Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general  occupational  hygiene No data available

Exposure controls  Personal protective equipment 
Engineering Control No data available
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Body Protection Protective clothing.
Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 480 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 69 minMaterial tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Respiratory protection
required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented
Other Protection  Measure No data available

Physical state Liquid
Colour Light yellow
Odour Pungent
Odor Threshold No data available
pH 14 at 100 g/l at 20 °C
Melting Point -30 °Ct. 
Boiling Point > 100 °C
Flash Point No data available 
Evaporation Rate No data available
Flammability (solid, gas) No data available
Explosive limits No data Available
Upper/lower flammability or explosive limits No data Available
Autoignition temperature No data available
Decomposition temperature  No data available 
Vapour pressure 226,636 hPa at 21,1 °C 546,596 hPa at 37,7 °C
Viscosity Dynamic 2,3 mPa.s at 15 °C
Density 1,18 g/mL at 25 °C
Relative Density No data available 
Specific Gravity No data available 
Partition coefficient No data available 
Explosive properties No data available 
Solubility No data available 
Ignition temperature No data available
Particle characteristics No data available 

Reactivity                        No data available
Chemical stability The product is chemically stable under standard ambient conditions (room temperature)
Possibilityof hazardous  reactions No data available
Conditions to avoid No data available
Incompatible materials
Bases, Amines, Alkali metals, Metals, permanganates, for example potassium permanganate, Fluorine, metal acetylides, hexalithium disilicideMetals
Hazardous decomposition products In the event of fire: see section 5

Acute toxicity  Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Skin corrosion/irritation Mixture causes burns.
Serious eye      damage/irritation Mixture causes serious eye damage. Risk of blindness!
Respiratory or skin    sensitization  No data available
Carcinogenicity No data available
Germ cell        mutagenicity  No data available
Reproductive toxicity  No data available
Specific target  organ  toxicity -   single    exposure  
Mixture may cause respiratory irritation.
Additional Information The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: MW4025000 Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.

Persistence and degradability No data available
Toxicity to fish  No data available
Toxicity to daphnia and other  aquatic invertebrates No data available
Toxicity No data available
Toxicity to bacteria   No data available
Toxicity to algae No data available1)
Products Biodegradation No data available
Mobility in soil No data availalble
Results of PBT and vPvB        assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting          properties  The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher
Other adverse effects No data available

Product See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
Contaminated packaging No data available
Waste treatment  Method No data available

UN number ADR/RID:1789 IMDG:1789

IATA:1789

UN proper    shipping  name  ADR/RID:HYDROCHLORIC ACID IMDG:HYDROCHLORIC ACID IATA:HYDROCHLORIC ACID
Transport hazard  class(es)               ADR/RID:8 IMDG:8               IATA:8
Packaging group ADR/RID:ll                          IMDG:ll IATA:ll
Environmental hazards ADR/RID:No                                    IMDG:No                                IATA:No
Special precautions for  user    Tunnel restriction code  (E)                                 
Further information No data available    

Safety, health and environmental    regulations/legislation specific for   the      substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment A Chemical Safety Assessment has been carried out for this substance.

Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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