a diesel fuel additive which improves Cetane number and offers the best performance in the most competitive way
Category
MSDS
| Product Name | : 2-Ethylhexyl nitrate |
| Part Number | : RXSOL-70-7030-210 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Sikka, Dahej, Hazira, JNPT, Goa, Mangalore, Cochin, Tuticorin, Chennai, Kakinada, Vizag, Paradip, Kolkata, UAE, Singapore.
| Phone | +91 22 27815540 / 41 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| 123@rxmarine.com | |
| Website | www.rxmarine.com |
| Name of Substance | Cas Number | EINECS No | Wt.% | Symbol |
| Cetane improver RX |
27247-96-7
27247-96-7
27247-96-7
|
248-363-6 | = 100 % | Xi |
| Classification according to Regulation (EC) No 1272/2008 | Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 4), H332 Acute toxicity, Dermal (Category 4), H312 Long-term (chronic) aquatic hazard (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16. |
| Labelling according Regulation (EC) No 1272/2008 | Pictogram Signal Word Warning |
| H302 + H312 + H332 | Harmful if swallowed, in contact with skin or if inhaled. |
| H411 | Toxic to aquatic life with long lasting effects. |
| P261 | Avoid breathing mist or vapors |
| P273 | Avoid release to the environment. |
| P280 | Wear protective gloves/ protective clothing. |
| P301 + P312 | IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. |
| P302 + P352 + P312 | IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. |
| P304 + P340 + P312 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. |
| Supplemental Hazard information (EU)EUH044 | Risk of explosion if heated under confinement. |
| EUH066 | Repeated exposure may cause skin dryness or cracking. |
| Reduced Labeling (= 125ml) | Pictogram Signal Word Warning |
| Hazard statement(s) | none |
| Precautionarystatement(s) | none |
| Supplemental Hazard information (EU) EUH044 | Risk of explosion if heated under confinement. |
| EUH066 | Repeated exposure may cause skin dryness or cracking |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Ecological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Toxicological information: Aldrich- 293784 Page 3 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. If breathing stops: mouth-to-mouth breathing or artificial respiration. Oxygen if necessary. Immediately call in physician. |
|
In case of skin contact
|
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| If swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Suitable extinguishing media | Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Carbon oxides Nitrogen oxides (NOx) Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning up |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
| Reference to other sections | For disposal see section 13. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary
measures against static discharge.
|
| Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands
and face after working with substance.
For precautions see section 2.2.
|
| Storage class | Storage class (TRGS 510): 10: Combustible liquids |
| Storage conditions | Tightly closed. |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Control parameters | Ingredients with workplace control parameters |
| Personal Protection |
Eye protection : Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses Body Protection : protective clothing Skin protection : required Respiratory protection : required when vapours/aerosols are generated.Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Control of environmental exposure | Do not let product enter drains. |
Gloves Suit
| Physical state | Liquid |
| Colour | Colourless to slightly Yellow |
| Odour | Acrid, slight odour of Sulphur dioxide |
| Meltingpoint/freezing point | No Data Available |
|
Initial boiling point
and boiling range
|
>100°C |
| Flammability (solid,gas) | No data available |
|
Upper/lower
flammability or
explosive limits
|
No data available |
| Flash point | 76,1 °C - Pensky-Martens closed cup - ASTM D 93 |
|
Autoignition
temperature
|
215 °C
at 1.013,25 hPa
|
|
Decomposition
temperature
|
No data available |
| pH | No data available |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: 1,7 mPa.s at 20 °C - ASTM D 445
|
| Water solubility | 0,0125 g/l at 20 °C - slightly soluble |
|
Partition coefficient:
n-octanol/water
|
log Pow: 5,24 |
| Vapor pressure | No data available |
| Density 0,963 g/cm3 at 25 °C - lit. Relative density | No data available |
| Relative vapordensity | No data available |
| Particlecharacteristics | No data available |
| Explosive properties | Risk of explosion if heated under confinement. |
| Oxidizing properties | none |
| Other safety information | No data available |
| Recativity | Forms explosive mixtures with air on intense heating. Risk of explosion if heated under confinement. A range from approx. 15 Kelvin below the flash point is to be rated as critical. |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibility of hazardous reactions | No data available |
| Incompatible materials | Organic materials, Powdered metalsStrong oxidizing agents |
| Hazardous Decomposition |
In the event of fire: see section 5 |
| Condition to Avoid | Strong heating. |
| Acute toxicity | LD50 Oral - Rat - 960 mg/kg LC50 Inhalation - 4 h - 11 mg/l - vapor (Acute toxicity estimate)LD50 Dermal - 1.100 mg/kg |
| Skin corrosion/irritation | Skin - Rabbit Result: No skin irritation - 4 h(OECD Test Guideline 404) |
| Serious eye damage/eye irritation |
No data available
|
| Respiratory or skin sensitization | Maximization Test - Guinea pig Result: Does not cause skin sensitization. (OECD Test Guideline 406) |
| Germ cell mutagenicity | Test Type: Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative |
| Carcinogenicity | No data available |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Specific target organ toxicity - repeated exposure | No data available |
|
Aspiration hazard
|
No data available
|
| Endocrine disrupting propertiesProduct: | Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: QU7925000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
| Toxicity | Toxicity to fish semi-static test LC50 - Danio rerio (zebra fish) - 2 mg/l - 96 h (OECD Test Guideline 203) Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - > 12,6 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae static test EC50 - Pseudokirchneriella subcapitata - 3,22 mg/l - 72 h (OECD Test Guideline 201)Toxicity to bacteria Growth inhibition EC50 - Sludge Treatment - > 1.000 mg/l - 3 h(OECD Test Guideline 209) |
| Persistence and degradability | Biodegradability aerobic - Exposure time 28 d Result: 0 % - Not readily biodegradable. (OECD Test Guideline 310) |
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
|
| Endocrine disrupting propertiesProduct: | Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Aldrich- 293784 Page 9 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Other adverse effects | No data available |
| Waste treatment methods | No data available |
| UN number | ADR/RID: 3082 IMDG: 3082 IATA: 3082 |
| UN proper shipping name |
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Ethylhexyl
nitrate)IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Ethylhexyl nitrate) IATA: Environmentally hazardous substance, liquid, n.o.s. (2-Ethylhexyl nitrate)
|
| Transport hazard class(es) | ADR/RID: 9 IMDG: 9 IATA: 9 |
| Packing group | |
| Packing group | ADR/RID: III IMDG: III IATA: III |
| Environmental hazards | |
| Environmental hazards | ADR/RID: yes IMDG Marine pollutant: yes IATA: yes |
| Special precautions for user |
Tunnel restriction code : (-)
|
| Further information | EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids. |
| Safety, health and environmental regulations/legislation specific for thesubstance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| National legislation | Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. E2 ENVIRONMENTAL HAZARDS |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.Take note of Dir 94/33/EC on the protection of young people at work |
| Chemical safety assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |