Carbon Disulfide is a clear, colorless to light yellow liquid with an unpleasant, rotten egg odor as a reagent or commercial grade. Pure Carbon Disulfide has a sweet, pleasant odor. It is used to make rayon, cellophane and other chemicals, as a solve
Category
MSDS
| Product Name | Carbon Disulfide |
| Part Number | RXSOL-33-3356-230 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
Substances
| Formula | CS2 |
| Molecular weight | 76,14 g/mol |
| CAS-No. | 75-15-0 |
| EC-No. | 200-843-6 |
| Index-No. | 006-003-00-3 |
| Component | Classification | Concentration |
| Carbon Disulfide | ||
|
CAS-No. 95-14-7
EC-No 202-394-1
Index-No. 006-003-00-3
|
Flam. Liq. 2; Acute Tox. 4;
Skin Irrit. 2; Eye Irrit. 2;
Repr. 2; STOT RE 1; H225,
H332, H315, H319,
H361fd, H372
Concentration limits:
>= 1 %: Repr. 2,
H361fd; >= 1 %: STOT RE
1, H372; 0,2 - 1 %:
STOT RE 2, H373;
|
= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
| Flammable liquids, (Category 2) | H225: Highly flammable liquid and vapor. |
| Acute toxicity, (Category 4) | H332: Harmful if inhaled. |
| Skin irritation, (Category 2) | H315: Causes skin irritation. |
| Eye irritation, (Category 2) | H319: Causes serious eye irritation. |
| Reproductive toxicity, (Category 2) |
H361fd: Suspected of damaging fertility.
Suspected of damaging the unborn child.
|
|
Specific target organ toxicity -
repeated exposure, (Category 1),
Peripheral nervous system,
Central nervous system, Cardiovascular system, Eyes
|
H372: Causes damage to organs through prolonged or repeated exposure. |
Label elements
| Signal Word | Danger |
|
Hazard Statements |
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H372 Causes damage to organs (Peripheral nervous system, Central nervous system, Cardio-vascular system, Eyes) through prolonged or repeated exposure.
|
|
Precautionary Statements |
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
|
| Supplemental Hazard Statements | None |
| Reduced Labeling (= 125 ml) | |
| Signal Word | Danger |
| Hazard statement(s) |
H372 Causes damage to organs through prolonged or repeated exposure.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
|
|
Precautionary
statement(s)
|
P202 Do not handle until all safety precautions have been read and understood.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
|
|
Supplemental Hazard
Statements
|
None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
Description of first aid measures
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
| If swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
Extinguishing media
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Carbon oxides
Sulfur oxides
Flash back possible over considerable distance., Container explosion may occur under fire
conditions., Vapors may form explosive mixture with air., May explode when heated.
Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.
|
| Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information |
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
|
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Environmental precautions | Do not let product enter drains. |
| Methods and materials for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
Precautions for safe handling
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
|
Conditions for safe storage, including any incompatibilities Storage conditions |
Tightly closed. Dry. |
| Storage class | Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Control parameters
Ingredients with workplace control parameters
Exposure controls
Personal protective equipment
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Chloroprene
Minimum layer thickness: 0,65 mm
Break through time: 480 min
Material tested:KCL 720 Camapren®
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Latex gloves
Minimum layer thickness: 0,6 mm
Break through time: 60 min
Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M). |
| Body Protection | Flame retardant antistatic protective clothing. |
| Respiratory protection |
Recommended Filter type: Filter A-(P3)
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Clear, liquid |
| Colour | Colorless |
| Odor | Odorless |
| Melting point/freezing point | Melting point/range: -112 - -111 °C |
| Initial boiling point and boiling range | 46 °C |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 60 %(V)
Lower explosion limit: 1 %(V)
|
| Flash point | -30 °C - c.c. |
| Autoignition temperature | No data available |
| Decomposition temperature |
415 °C
Decomposition energy (Mol): 89,7 kJ/mol
Method: OECD Test Guideline 113
|
| pH | No data available |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | 2,9 g/l at 20 °C - OECD Test Guideline 105- soluble |
| Partition coefficient: n-octanol/water |
log Pow: 2,7 at 25 °C - OECD Test Guideline 117 -
Bioaccumulation is not expected.
|
| Vapor pressure | 274 hPa at 25 °C - OECD Test Guideline 104 |
| Density | 1,266 g/mL at 25 °C |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | None |
| Other safety information | |
| Surface tension |
71,9 mN/m at 1g/l at 19,5 °C
- OECD Test Guideline 115
|
| Reactivity |
Vapors may form explosive mixture with air.
|
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibility of hazardous reactions |
Risk of explosion with:
nitrogen oxides
permanganic acid
Oxidizing agents
halogen-halogen compounds
halogen oxides
Iron
ferric oxide
Chlorine
hydrazines
powdered aluminium
chlorine oxides
Potassium
potassium permanganate
Lithium
sodium
nitrogen dioxide
azides
Risk of ignition or formation of inflammable gases or vapours with:
Fluorine
phosphorus
sulfur
Activated charcoal
Powdered metals
Reducing agents
Exothermic reaction with:
Zinc
Acids
|
| Conditions to avoid |
Exposure to light may affect product quality.
Strong heating.
|
| Incompatible materials |
No data available
|
| Hazardous decomposition products | In the event of fire: see section 5 |
Information on toxicological effects
| Acute toxicity |
LD50 Oral - Rat - male and female - 500 mg/kg
(OECD Test Guideline 423)
LC50 Inhalation - Rat - 4 h - > 1,5 mg/l - dust/mist
Remarks: (RTECS)
LD50 Dermal - Rabbit - > 2.000 mg/kg
Remarks: (External MSDS)
|
| Skin corrosion/irritation |
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
|
| Serious eye damage/eye irritation |
Eyes - Rabbit
Result: Irritating to eyes. - 24 h
(OECD Test Guideline 405)
|
| Respiratory or skin sensitization |
Maximization Test - Guinea pig
Result: negative
(OECD Test Guideline 406)
|
| Germ cell mutagenicity |
Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Test Type: Micronucleus test
Species: Mouse
Method: OECD Test Guideline 474
Result: negative
|
| Carcinogenicity | No data available |
| Reproductive toxicity |
No data available
|
| Teratogenicity | No data available |
| Specific target organ toxicity (single exposure) | No data available |
| Specific target organ toxicity (repeated exposure) | No data available |
| Aspiration hazard | No data available |
| Additional information | |
|
Endocrine disrupting properties
Product
|
|
| Assessment |
The substance/mixture does not contain
components considered to have endocrine
disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU)
2018/605 at levels of 0.1% or higher.
RTECS: DM1225000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
Systemic effects:
After absorption:
Nausea
Vomiting
Cyanosis
Drowsiness
Dizziness
Diarrhea
Shortness of breath
Other dangerous properties can not be excluded.
Handle in accordance with good industrial hygiene and safety practice.
|
| Toxicity | |
| Toxicity to fish | Semi-static test LC50 - Danio rerio (zebra fish) - 180 mg/l - 96 h (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | static test EC50 - Daphnia galeata (Water flea) - 8,58 mg/l - 48 h (OECD Test Guideline 202) |
| Toxicity to algae |
Growth inhibition ErC50 - Selenastrum capricornutum (green algae) -75 mg/l - 72 h
(OECD Test Guideline 201)
IC50 - Desmodesmus subspicatus (green algae) - 231 mg/l - 72 h
Remarks: (External MSDS)
|
| Toxicity to bacteria | EC50 - activated sludge - 1.060 mg/l (OECD Test Guideline 209) |
| Persistence and degradability | |
| Biodegradability |
Aerobic - Exposure time 28 d
Result: 0 % - Not readily biodegradable.
(OECD Test Guideline 301D)
|
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
|
Endocrine disrupting properties
Product
|
|
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No data available |
| Waste treatment Method | No data available |
| UN number | ADR/RID:3077 IMDG:3077 IATA: 3077 |
| UN proper shipping name |
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1HBenzotriazole)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1HBenzotriazole)
IATA: Environmentally hazardous substance, solid, n.o.s. (1H-Benzotriazole) |
| Transport hazard class(es) | ADR/RID: 9 IMDG: 9 IATA:9 |
| Packaging group | ADR/RID: IIl IMDG: lII IATA:IIl |
| Environmental hazards | ADR/RID: yes IMDG Marine pollutant: yes IATA: yes |
| Special precautions for user | No data available |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |