Biocide for Oily Water

Product

EINECS /

ELINCS NO

SYMBOL

R-PHRASES /

NOTAS

% (w/w)

Quaternary Ammonium compound

Proprietary

    C, N

R22, R34, R50

10 - 30

Ethylene Glycol

203-473-3

Xn

R22

10 - 30

Isopropanol 

200-661-7

F, Xi

R11, R36, R67

10- 5

Quaternary phosphorus compound

Proprietary

R23, R22, R41,R43, R63, R50

1 - 5

Dipropylene Glycol Monomethyl Ether

252-104-2

OEL

HAZARD CLASSIFICATION :

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Flammable. Harmful if swallowed. Causes burns. May cause sensitization by skin contact

HUMAN HEALTH HAZARDS - ACUTE :

INHALATION :

Irritating, in high concentrations, to the eyes, nose, throat and lungs.

SKIN CONTACT :

May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals

EYE CONTACT

Corrosive. Will cause eye burns and permanent tissue damage

INGESTION :

Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. Harmful if swallowed. Large quantities may cause kidney damage.

HUMAN HEALTH HAZARDS - CHRONIC

Contains ethylene glycol (EG). Repeated high dose exposure to EG by ingestion (animal studies) has caused kidney damage, brain damage, degeneration of the liver, changes in blood chemistry and circulating blood cells. Prolonged and/or repeated exposures may cause similar effects in humans. Ethylene glycol has been shown to cause developmental and reproductive effects at high dose levels in laboratory animals. The relationship of these results to humans has not been fully established. Prolonged exposure to ethylene glycol may cause central nervous system, kidney and liver effects.

PHYSICAL AND CHEMICAL HAZARDS

Flammable

INHALATION :

Get medical attention. Remove to fresh air, treat symptomatically

SKIN CONTACT

Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use

 EYE CONTACT

Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open

INGESTION

Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink.

NOTE TO PHYSICIAN

Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition

FLASH POINT :

50 °C PMCC

EXTINGUISHING MEDIA 

Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water spray or fog, thoroughly drenching the burning material. Water mist may be used to cool closed containers

FIRE AND EXPLOSION HAZARD

Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit

PERSONAL PRECAUTIONS

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities

METHODS FOR CLEANING UP

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations)

ENVIRONMENTAL PRECAUTIONS

 Do not contaminate surface water

HANDLING

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labelled. Do not use, store, spill or pour near heat, sparks or open flame

STORAGE CONDITIONS

Store in suitable labelled containers. Store the containers tightly closed. Store away from heat and sources of ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be grounded to avoid electrical charges

SUITABLE CONSTRUCTION MATERIAL

HDPE (high density polyethylene), PTFE, FEP (encapsulated), Viton, Stainless Steel 304, Stainless Steel 316L, MDPE (medium density polyethylene), Surface-modified HDPE (high density polyethylene), Nitrile, EPDM, Perfluoroelastomer, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use

UNSUITABLE CONSTRUCTION MATERIAL

Carbon Steel C1018

Method

Absorbant

US NIOSH: 5523

XAD-7 / Glass fibre
filter OVS tube

US NIOSH: 1400

Charcoal

US OSHA: 101

Charcoal

BIOLOGICAL EXPOSURE INDICES

Isopropanol

A biological index of exposure to isopropyl alchohol (CAS 67-63-0) is the detection of acetone in the blood or urine post shift (50mg/l)

 ENGINEERING MEASURES

 General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces.

  GENERAL ADVICE

 The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166.

  RESPIRATORY PROTECTION

 Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: A-B-E-K-P The applicable European standard can be found in EN 141, EN 143 and EN 371. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection

 HAND PROTECTION

 When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE  manufacturers. The applicable European standard can be found in EN 374

When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN 467 and EN 345

EYE PROTECTION

When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN 467 and EN 345

Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area  Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke

VISCOSITY

ASTM D-97 -13 °C

MATERIALS TO AVOID

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors

HAZARDOUS DECOMPOSITION PRODUCTS

Under fire conditions

Oxides of carbon, Oxides of nitrogen, Oxides of phosphorus

PERSISTENCY AND DEGRADATION

The organic portion of this preparation is expected to be readily biodegradable

BIOACCUMULATION POTENTIAL

Component substances have a low potential to bioconcentrate

Isopropanol, Quaternary Ammonium compound

Hazard Class - Secondary

Packing Group

ADR/RID H.I.n. :

CLASSIFICATION CODE

AIR TRANSPORT (ICAO/IATA)

Proper Shipping Name

FLAMMABLE LIQUID, CORROSIVE, N.O.S

Technical Name(s) :

Isopropanol, Quaternary Ammonium compound

UN/ID No

UN 2924

Hazard Class - Primary

Hazard Class - Secondary

Packing Group

IATA Cargo Packing Instructions

310

IATA Cargo Aircraft Limit

60 L (Max net quantity per package)

IATA Passenger Packing Instructions

Y309 / 309

IATA Passenger Aircraft Limit

1 L / 5 L

MARINE TRANSPORT (IMDG/IMO)

Proper Shipping Name

FLAMMABLE LIQUID, CORROSIVE, N.O.S.

Technical Name(s) :

Isopropanol, Quaternary Ammonium compound

UN/ID No

UN 2924

Hazard Class - Primary

Hazard Class - Secondary

Packing Group

OTHER APPLICABLE INFORMATION

CEFIC TREMCARD REFERENCE

30GFC-III

EMERGENCY ACTION CODE

3W

R10

Flammable.

R22

Harmful if swallowed

R34

Causes burns

R43

May cause sensitization by skin contact

SAFETY PHRASES

S26

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39

Wear suitable protective clothing, gloves and eye/face protection.

S45 

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

INTERNATIONAL CHEMICAL CONTROL LAWS

UNITED STATES

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

CANADA

This product contains substance(s) which are found on the Non-Domestic Substances List (NDSL), or are not in compliance with other Canadian Acts

EUROPE

The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories

JAPAN

All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).