Anti Rust And Corrosion Preparation

Anti Rust And Corrosion Preparation
MSDS

Product Name Anti Rust And Corrosion Preparation
   

Company Details:

RXSOL CHEMO PHARMA INTERNATIONAL
356 TTC INDUSTRIAL AREA MIDC PAVNE ,
NEW BOMBAY 400709 INDIA

Phone +91 22 20871200
Fax +91 27612100 :::AOH :0091 9821214367
Email 123@rx-sol.com/ 


 

Name     of        Substance                          Cas Number EINECS No Wt.% Symbol
Phosphoric acid 7664-38-2 231-633-2 70 -80 %  C
2-phosphonobutane-1,2,4-tricarboxylic acid 37971-36-1 2653-733-5 10 - 30%  Xn
Non Haz Emulsifier Properitory   20 - 30%  

 

 

Signal Word                        None
Hazard Statements


H335       May cause respiratory irritation.
H302       Harmful if swallowed.
H411       Toxic to aquatic life with long lasting effects.
H314       Causes severe skin burns and eye damage.

Precautionary statements - prevention P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
Precautionary statements - response P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.Storage: Store locked up. Disposal: P501 Dispose of contents/container in accordance with local regulations.

  

 

Eye Contact Immediately hold eyelids apart and flush the eye continuously with running water.Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact Immediately flush body and clothes with large amounts of water, using safety shower if available.Quickly remove all contaminated clothing, including footwear. ash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Cntre.Transport to hospital, or doctor.
Inhalation:              Lay patient down. Keep warm and rested.Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.
Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone
derivative may be considered.
Ingestion: For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.
Notes to Physicians Treat symptomatically.

 

Suitable extinguishing media Water spray or fog.
Foam.
Dry chemical powder.
Protective  Equipment                       Use personal protective equipment.
Hazardous combustionproducts Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Fire/Explosion Hazard Combustible.
Slight fire hazard when exposed to heat or flame.
Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Combustion products include: amp;43cw carbon dioxide (CO2)phosphorus oxides (POx) other pyrolysis products typical of burning organic material.

 

 

Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. Wear suitable personal protective equipment.Respiratory protective equipment.

Enviromental  Precaution  Do not allow contact with soil, surface or ground water.If the products get into drains, inform the relevant authorities immediately.
Methods and materials for
containment and cleaning up

Minor Spill : Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

Mazor Spill : Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus.

 

Advice on safe handling Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Storage

Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.

DO NOT use aluminium or galvanised containers
Check regularly for spills and leaks
Lined metal can, lined metal pail/ can. Plastic pail. Polyliner drum.

Storage  incompatibility Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may form an explosive mixture with air.
Avoid strong bases.
Segregate from alkalies, oxidising agents and chemicals readily decomposed by acids, i.e. cyanides, sulfides, carbonates.
Advice on general occupational hygiene Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas.

 

 

Engineering Control Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk.
Personal   Protection

Eye & Face  protection : Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories; spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there is a danger of splashing, or if the material may be under pressure. Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properly fitted. Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; these afford face protection.

Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Exposure Limits:
 
Source Ingredients Material Name TWA STEL Peak
European Union (EU)
First List of Indicative
Occupational Exposure Limit Values (IOELVs) (English)
Phosphoric acid Orthophosphoric acid 1
mg/m3
 
 2 mg/m3 Not
Available
EU Consolidated List of Indicative Occupational
Exposure Limit Values
(IOELVs)
 Phosphoric acid  Orthophosphoric acid 1
mg/m3
2 mg/m3 Not
Available
Norway regulations on action values and limit values for physical andchemical factors in the work environment and infection risk groups for biological factors (Norwegian)  Phosphoric acid  Orthophosphoric acid 1
mg/m3
2 mg/m3  Not
Available
Norway regulations on action values and limit values for physical andchemical factors in the work environment and infection risk groups for biological factors (Norwegian)  zinc chloride  Sinkklorid 1
mg/m3
Not
Available
Not
Available
Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.

       gloves                suit                

            Gloves                       Suit                          

  

 

Appearance         Colourless to yellow, miscible with water
Physical state      Liquid
Odour Not Available
Odour threshold Not Available
Boiling point and boiling range  100°C
Flash Point No Data Available
Freezing Point No Data Available
pH 2
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper explosion limit No data available
Lower explosion limit No data available
Explosive properties No data available
Vapor pressure No data available
Relative vapor density No data available
Relative density 1.8
Water solubility Soluble
Solubility in other solvents No data available
Partition coefficient: octanol No data available
Autoignition temperature No data available
Thermal decomposition No data available
Viscosity, kinematic No data available
Explosive properties No data available
Oxidizing properties No data available
Molecular weight No data available
VOC No data available

 

 

Recativity                                             None
Stability Stable under normal  conditions.
Possibility of hazardous reactions No dangerous reaction known under conditions of normal use.
Incompatible materials See Section 7
Hazardous Decomposition

carbon dioxide (CO2)
phosphorus oxides (POx)
other pyrolysis products typical of burning organic material.

Condition to Avoid Strong Alkaline material and Oxidizing Material
Polymerization Will not occur.

 

Route of Exposure Inhalation, Eye contact, Skin contact
Eyes                                    

Direct eye contact with acid corrosives may produce pain, tears, sensitivity to light and burns. Mild burns of the epithelia generally recover rapidly and completely.

Skin Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with the formation of scar tissue.
Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models). Systemic harm, however, has been identified following exposure of animals by at least one other route and the material may still produce health damage following entry through wounds, lesions or abrasions. Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Ingestion  Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual. Ingestion of acidic corrosives may produce burns around and in the mouth, the throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident.
Inhalation The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. Corrosive acids can cause irritation of the respiratory tract, with coughing, choking and mucous membrane damage. There may be dizziness, headache, nausea and weakness.
Chronic Exposure Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and/or ulceration of mouth lining. Irritation of airways to lung, with cough, and inflammation of lung tissue often occurs. Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
Acute oral toxicity No data available
Acute inhalation toxicity No data available
Acute dermal toxicity No data available
Classification The classification was made by the conventional (calculation) method of Dangerous Preparations Directive(1999/45/EC)


 

Toxicity
Ingredient  Endpoint Test Duration (hr)   Species Value Source
phosphoric acid.. %             LC50  96  Fish 75.1mg/L 2

phosphoric acid ..%,

EC50 48 Crustacea >376mg/L 2

phosphoric acid ..%,

EC50 72 Algae or other aquatic plants 77.9mg/L 2

phosphoric acid ..%,

EC50 24 Crustacea >376mg/L 2

phosphoric acid ..%,

NOEC 72 Algae or other aquatic plants 7.5mg/L 2

2-phosphonobutane-
1,2,4-tricarboxylic acid

LC50 96 Fish  3.71293mg/L 3
2-phosphonobutane-
1,2,4-tricarboxylic acid
EC50   48 Crustacea >1071mg/L 2
2-phosphonobutane-
1,2,4-tricarboxylic acid
EC50 96 Algae or other aquatic plants 4.0015mg/L 3
zinc chloride  LC50 96 FISH 0.03mg/L 4
zinc chloride EC50 48 Crustacea 0.045mg/L 4
zinc chloride EC50 24 Algae or other aquatic plants 0.0004mg/L 4
zinc chloride NOEC 216 Algae or other aquatic plants >0.0001mg/L 4

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites.

Ecotoxicity The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines are between 6.0 and almost 9. Acute testing with fish showed 96h-LC50 at about pH 3.5 Prevent, by any means available, spillage from entering drains or water courses.
Toxicity to daphnia  and others No data available
Toxicity to algae                       No data available
Biodegradability  Medium
Persistence and degradability No data available
Bioaccumulative potential phosphoric acid ... %, orthophosphoric acid ...% LOW (LogKOW = -0.7699)
2-phosphonobutane- 1,2,4-tricarboxylic acid LOW (LogKOW = -1.359)
zinc chloride HIGH (BCF = 16000)
Mobility in soil phosphoric acid ... %,
orthophosphoric acid ...HIGH (KOC = 1)
2-phosphonobutane-1,2,4-tricarboxylic acid LOW (KOC = 846)
zinc chloride LOW (KOC = 23.74)

 

 

Remarks Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.
Waste Disposal The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility

 

UN        Number                                          Not Regulated for Transport
Proper shipping name Anti Rust And Corrosion Preparation
Transport hazard class(es)
ADR/RID Not Regulated
Subsidiary risk IMDG Not Regulated
Subsidiary risk IATA  Not Regulated
Packing group
Packing group NA
Environmental hazards
Environmental hazards No
Marine pollutant No
ADR/RID
Hazard ID NA
Tunnel Category (E)
IMDG
EmS Code NA
IATA
Packing Instruction (Cargo) 856
Maximum quantity 60 L
Packing Instruction (Passenger) 852
Maximum quantity 5 L 

 

 

 

Regulations This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : 98/24/EC, 92/85/EC, 94/33/EC, 91/689/EEC, 1999/13/EC, Commission Regulation (EU) 2015/830, Regulation (EC) No 1272/2008 and their amendments
Chemical safety assessment

Chemical Safety Assessment not carried out

Further information FOR INDUSTRIAL USE.
 

 

 

Other Information  

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  we assume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rxsol Chemo Pharma International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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