TRI CHLORO ETHYLENE

Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA   

Stock Point : Mumbai, Kandla, Kolkata, Chennai, Vizag, Fujairah, Muscat, Nairobi   

Substance:

Hazardous components (REGULATION (EC) No 1272/2008):

For the full text of the H-Statements mentioned in this Section, see Section16 :

Hazardous components (1999/45/EC) :

For the full text of the R-phrases mentioned in this Section, see Section 16:

Mixture:
not applicable

Classification of the substance or mixture:
Classification (REGULATION (EC) No 1272/2008):
Carcinogenicity, Category 1B, H350
Germ cell mutagenicity, Category 2, H341
Specific target organ toxicity - single exposure, Category 3, Central nervous system, H336  Skin irritation, Category 2, H315
Eye irritation, Category 2, H319
Chronic aquatic toxicity, Category 3, H412

For the full text of the H-Statements mentioned in this Section, see Section16:

Classification (67/548/EEC or 1999/45/EC):

For the full text of the R-phrases mentioned in this Section, see Section 16:

Label elements:
Labelling (REGULATION (EC) No 1272/2008):

Hazard pictograms:
Signal word:
Danger
 
Hazard statements:
H350 May cause cancer.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements:
Prevention:
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Restricted to professional users.

Reduced labelling (≤125 ml):
Hazard pictograms
Signal word
Danger

Hazard statements:
H350 May cause cancer.
H341 Suspected of causing genetic defects.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements:
P201 Obtain special instructions before use.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Restricted to professional users.

Other hazards:
None known.
 

Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture
Not combustible.
Ambient fire may liberate hazardous vapours.
Fire may cause evolution of:
Hydrogen chloride gas

Advice for firefighters:
Special protective equipment for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information:
Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

Personal precautions, protective equipment and emergency procedures:

Control parameters:
Components with workplace control parameters Components Basis Value Threshold limits Remarks

trichloroethylene (79-01-6):

Derived No Effect Level (DNEL) Worker DNEL:acute Systemic effects inhalation 164.1

Recommended monitoring procedures
Methods for measurement of the workplace atmosphere have to correspond to the requirements of norms DIN EN 482 and DIN EN 689.
Predicted No Effect Concentration (PNEC):

Exposure controls:
Engineering measures:
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.
See section 7.1.

Individual protection measures:
Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.

Eye/face protection:
Safety glasses

Hand protection:

The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 890 Vitoject® (full contact), KCL 730 Camatril® -Velours (splash contact).The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types.This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves

Other protective equipment:
protective clothing

Respiratory protection:
required when vapours/aerosols are generated.Empfohlener Filtertyp: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Environmental exposure controls:
Do not empty into drains.
 


 Information on basic physical and chemical properties:

Other data:
Ignition temperature
410 °C

Information on toxicological effects :
Acute oral toxicity:
LD50 rat: 4,920 mg/kg (IUCLID)
LDLO human: 7,000 mg/kg (RTECS)

absorption:
Symptoms: Nausea, Vomiting, Risk of aspiration upon vomiting., Aspiration may cause pulmonary oedema and pneumonitis.

Acute inhalation toxicity:
LC50 rat: 43.84 mg/l; 4 h (IUCLID)

Symptoms: Possible damages:, mucosal irritations, After a latency period:, Lung oedema

Acute dermal toxicity:
LD50 rabbit: > 29,000 mg/kg (IUCLID)
absorption
Skin irritation
rabbit
Result: Severe irritations
(IUCLID)
Drying-out effect resulting in rough and chapped skin.
Causes skin irritation.
Eye irritation
rabbit
Result: Eye irritation
(IUCLID)
Causes serious eye irritation.
Sensitisation
This information is not available.
Germ cell mutagenicity
Genotoxicity in vitro
Ames test
Result: negative
(IUCLID)

Carcinogenicity:
This information is not available.

Reproductive toxicity:
This information is not available.
Teratogenicity
This information is not available.
CMR effects

Carcinogenicity:
May cause cancer.

Mutagenicity:
Suspected of causing genetic defects.
Specific target organ toxicity - single exposure

Target Organs: Central nervous system
May cause drowsiness or dizziness.
Specific target organ toxicity - repeated exposure
This information is not available.

Aspiration hazard:
This information is not available.

Further information:
After absorption:
Headache, Dizziness, Cardiac irregularities, Nausea, agitation, spasms, inebriation, narcosis
Absorption can result in damage to:
Liver, Kidney
After long-term exposure to the chemical:

Toxic effect on:
Central nervous system

Further data:
Handle in accordance with good industrial hygiene and safety practice.

Toxicity:
Toxicity to fish:
LC50 Pimephales promelas (fathead minnow): 41 mg/l; 96 h (ECOTOX Database)
Toxicity to daphnia and other aquatic invertebrates
EC50 Daphnia magna (Water flea): 18 mg/l; 48 h (IUCLID)
Toxicity to algae:
IC50 Pseudokirchneriella subcapitata (green algae): 175 mg/l; 96 h (IUCLID)
Toxicity to bacteria:
EC50 Photobacterium phosphoreum: 975 mg/l; 5 min (IUCLID)

Persistence and degradability:
Biodegradability:
19 %; 28 d
OECD Test Guideline 301D
Not readily biodegradable.
4 %; 28 d
Zahn-Wellens Test:
Not readily eliminated from water.

Bioaccumulative Potential:
Partition coefficient: n-octanol/water
log Pow: 2.29
(experimental)
(IUCLID) Bioaccumulation is not expected.

Mobility in soil:
Distribution among environmental compartments
Adsorption/Soil
log Koc: 1.97
(experimental)
Mobile in soils

Results of PBT and vPvB assessment:
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.

Other adverse effects:
Henry constant
998 Pa*m³/mol
(Lit.) Distribution preferentially in air.
Additional ecological information
Discharge into the environment must be avoided.

Waste treatment methods:
Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
 

 Land transport (ADR/RID):

Inland waterway transport (ADN): Not relevant

Air transport (IATA):

 Sea transport (IMDG):

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code:
Not relevant

EU regulations:

Chemical Safety Assessment:
For this product a chemical safety assessment was not carried out.

The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the individual constituents The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in terms of safety requirements and does not signify any warranty with regard to the product's properties The data given here only applies when product used for proper application(s). The product is not sold as suitable for other applications usage in such may cause risks not mentioned in this sheet. Do not use for other application(s) without seeking advice from manufacturer.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.